<?xml version="1.0" encoding="UTF-8"?>
<ProductCatalog>
  <Product>
    <ProductCode>PMP7170B3G_DUO</ProductCode>
    <Vendor>PRESTIGIO</Vendor>
    <AttrList>
      <element Name="Manufacturer Article" Value="PMP7170B3G_DUO"/>
      <element Name="Manufacturer" Value="PRESTIGIO"/>
      <element Name="Product Type" Value="PC Tablet"/>
    </AttrList>
    <Images>
      <Image>https://content.iytrfit.com/pimg/s/resize/900x900x900x900/130722140024967327.jpg</Image>
      <Image>https://content.iytrfit.com/pimg/s/resize/900x900x900x900/130722140024953946.jpg</Image>
      <Image>https://content.iytrfit.com/pimg/s/resize/900x900x900x900/130722140024941190.jpg</Image>
    </Images>
  </Product>
  <Product>
    <ProductCode>CF/4GB</ProductCode>
    <Vendor>KINGSTON</Vendor>
    <AttrList>
      <element Name="Memory Technology" Value="NAND Flash"/>
    </AttrList>
    <Images>
      <Image>https://content.iytrfit.com/pimg/s/resize/160x160x160x160/70717084617228035.jpg</Image>
    </Images>
  </Product>
</ProductCatalog>

$newfile = "xml/cena.xml";
$xml = simplexml_load_file($newfile) or die("url not loading");
foreach($xml->Product as $child)
  {
  $name = $child->ProductCode;
  $vendor = $child->Vendor;
  }

$newfile = "xml/cena.xml";
$xml = simplexml_load_file($newfile) or die("url not loading");
foreach($xml->Product as $child)
  {
  $name = $child->ProductCode;
  $vendor = $child->Vendor;
  echo $child->AttrList;// вот тут вообще не представляю что делать
     foreach($xml->Product->Images as $child2)
     {
         echo $child2->Image;// вот один из вариантов кол-во записей совпадает но везде выводит самый первый url картинки
     }
  }